Accelerator |
A chemical added to the mix of
rubber, fillers, sulphur, zinc oxide etc., to speed
up the vulcanization process. |
Activator |
A chemical added to the mix
of rubber, fillers etc. to ‘kick off’
the vulcanization process. |
Antidegradent |
A general word for antioxidants
and antiozonants. |
Antioxidant
|
A chemical present in the compound
and vulcanizate that will slow down the rate of oxidative
degradation. It interferes with the chain of chemical
reactions that cause degradation and must therefore
be intimately dispersed throughout the mix. It has
essentially no effect on degradation by ozone |
Antiozonant |
A chemical present in the compound
and vulcanizate that will slow down or halt degradation
by ozone. Antiozonants function by migrating to the
surface of the vulcanized rubber product and then,
either without chemical reaction (waxes) or after
reaction with ozone, form an ozone-impermeable barrier
or skin on the rubber surface. If the skin is cracked
by abrasion, flexing or cleaning degradation will
occur until the antiozonant has migrated from the
bulk of the product to repair the damage. They offer
little or no protection against oxidative degradation. |
Atom |
The smallest unit an element
can be divided into and still retain the unique identity
of that element. Atoms can be further split into a
number of sub-atomic particles but these are common
to all elements. It is the particular combination
of sub-atomic particles that defines each element. |
CIS/TRANS |
When two carbon atoms in a molecule
are joined by a double (C=C), rather than a single
(C-C) bond, the OLEFINIC or ‘ENE’ linkage
has two important properties. Firstly, the remaining
two bonds from each carbon atom lie in the same plane
( >C=C< ) and secondly, the bond is rigid so
the carbon atoms cannot rotate relative to each other.
In a polymer chain one of each of the ‘free’
carbon bonds will form part of the chain whilst the
others will be attached to a hydrogen or other relatively
small atom or group of atoms. If the two polymer chain
fragments are on the same side of the double bond
(i.e. both above or both below in the illustration
above) then the bond is called a CIS bond or CIS linkage.
If they are on opposite sides (one above and one below)
it is TRANS. This can have a substantial effect on
the properties of the polymer. For instance, natural
rubber has an ‘all CIS’ configuration
whilst gutta percha has an identical chemical composition
but the isoprene molecule is in the ‘all TRANS’
configuration. |
Compound or Mix |
A mixture of rubber and all the
additives which will be in the final vulcanized product
but before heat is applied to effect the cure. |
Curing &
Vulcanization |
The CURING process was so named
by Charles Goodyear when he discovered that a mixture
of natural rubber, white lead and sulphur, when heated,
cured rubber of its two main commercial disadvantages,
it turned sticky when hot and turned brittle when
cold. It also prevented or delayed putrefaction. Hancock,
in the UK, called the process VULCANIZATION after
a suggestion by Mr Brockedon. Today the term ‘VULCANIZATION’
is restricted to sulphur cures of elastomers whilst
the term ‘CURING’ is applied to any process
where a three dimensional network is built up from
polymer chains. |
Elastomer |
This term is used to describe
any rubber or rubber-like material. |
Extending Oil |
Extending oils can be added to
elastomers to soften them. Manufacturers are always
balancing cost against performance and it is possible
to take an elastomer, add considerable amounts of
(cheap) filler, which makes the product hard, and
then soften it down with (cheap) oil. Performance
acceptable, price less or margin more! |
Fillers |
Inorganic materials such as calcium
carbonate (whiting) and clay, as well as carbon black,
which are added to plastics and elastomers to ‘bulk
them out’. A few fillers such as carbon black
interact with the elastomers to give a mixture which
has more strength than would be expected and these
are called reinforcing fillers. |
Molecule |
A number of atoms (2 or more)
joined together in a particular way to uniquely define
a chemical moiety. For instance, 2 carbon atoms, 6
hydrogen atoms and 1 oxygen atom can be joined in
the order CH3-CH2-OH (ethyl alcohol) but also as CH3-O-CH3
(dimethyl ether). |
Monomer |
A small molecule which is the
basic ‘building block’ of a polymer chain. |
Pre- &
Post Vulcanization |
Latex can be vulcanized over
a period of several hours by the addition of the usual
ingredients – sulphur, zinc oxide and an accelerator
– to the warm latex. Visually the vulcanized
latex appeared indistinguishable from the untreated
material but when it was coagulated and/or dried it
behaved as if vulcanized. The procedure of treating
the latex in this way is called pre-vulcanization
and any further short heating period after coagulation,
post-vulcanization. |
Plasticisizer |
Some plastic materials are quite
hard and non-elastic. However, when an appropriate
solvent is added the resulting material takes on rubber-like
properties. The solvent is called a plasticizer. |
POLYMERS: |
|
Homopolymer |
A nominally linear chain (but
often with some branching) of many hundreds or thousands
of one specific monomer. Written as (monomer)n. Thus
the monomer ethylene (C2H4) becomes polyethylene (polythene)
(C2H4)n. Natural rubber is a homopolymer with the
chemical structure (C5H8)n. |
Copolymer |
If two different monomers are
mixed together before being polymerized the chain
will have the different monomers distributed randomly
along its length. This is a copolymer. If butadiene
and styrene are co-polymerized the result is styrene
butadiene rubber (SBR). |
Block Copolymer |
Sometimes individual monomers
may be polymerised to form short chains and then these
chains mixed and further polymerised so that the final
polymer has a ‘blocky’, rather than random
distribution. If styrene and butadiene are polymerised
in this way, the rubber produced is called styrene
butadiene styrene rubber (SBS). This technique can
also be used to prepare branched chains and ultimately
‘STAR COPOLYMERS’ of styrene. |
Terpolymer |
If three monomers are mixed,
the resulting polymer is a terpolymer. The copolymerisation
of ethylene and propylene gives ethylene propylene
rubber (EPR) but this has no residual double bonds
where crosslinking can occur. The addition of a third
monomer, at a low level of 3 to5%, gives the terpolymer
EPDM which can be crosslinked. |
Addition Polymer |
An addition polymer is one resulting
from the joining together of its monomers without
the loss of any components of the monomers i.e. n
monomers of C2H4 go to (C2H4)n. |
Condensation Polymer |
Some polymers have a regular
A-B-A-B-A structure where ‘A’ is a monomer
with two (or more) functional groups and ‘B’
is another monomer with two (or more) complementary
functional groups. ‘A’ and ‘B’
react together with the elimination of a small molecule
such as water from each complementary pair of groups.
The elimination of water was noted in some early investigations
of this chemistry and led to the name ‘condensation’
for this general type of reaction. |
Rubber |
‘Rubbery’ polymers
are defined as those materials which can be crosslinked
to provide a three dimensional network and yet still
retain a high extensibility coupled with an ability
to recover quickly their original shape – what
is generally called their elastic property. |
Rubber-like Material |
Describes those polymers which
retain a high extensibility coupled with an ability
to recover quickly their original shape but are not
crosslinked. |
TRANS/CIS |
See CIS/TRANS above. |
Vulcanization |
See CURING & vulcanization
and PRE- & POST-VULCANIZATION above. |